silver hydrogen maleate | 55135-60-9

• 英文名称: silver hydrogen maleate
• 英文别名: [Ag(μ3-HMa)]n；[Ag(μ3-malonic acid-H)]n；Silver maleate；silver;(Z)-4-hydroxy-4-oxobut-2-enoate
• CAS: 55135-60-9
• 化学式: Ag*C₄H₃O₄
• 分子量: 222.934
• InChiKey: IZXSLAZMYLIILP-ODZAUARKSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.63
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.4
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  silver hydrogen maleate 以 neat (no solvent, solid phase) 为溶剂， 生成 银
  参考文献：
  名称：

  Silver nanoparticles from the thermal decomposition of a two-dimensional nano-coordination polymer

  摘要：

  Nanostructures of the two-dimensional coordination polymer [Ag(mu(3)-Hma)](n) (1) [H(2)ma = maleic acid] have been synthesized by the reaction of KHma and AgNO3 by a sonochemical process and with oleic acid treatment at 453 K. The single-crystal X-ray data of compound 1 shows the formation of a hemi paddlewheel structure. The coordination number of the Ag-1 ions in compound 1 is three and there is an argen-tophillic interaction. Silver nanostructures and silver nanoparticles were synthesized by calcination and thermal decomposition of the compound 1 nanostructures, respectively. These nanostructures and nanoparticles were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The thermal stability of compound 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.09.011
• 作为产物：
  描述：

  顺丁烯二酸 、 silver carbonate 以 水 为溶剂， 生成 silver hydrogen maleate
  参考文献：
  名称：

  Oliinik; Mys'kiv, Russian Journal of Inorganic Chemistry, 1996, vol. 41, # 3, p. 381 - 384

  摘要：

  DOI：
• 作为试剂：
  描述：

  1,4-bis(2'-chloroethyl)-1,4-diazabicyclo-<2.2.1>heptane dichloride 、 silver hydrogen maleate 在 silver hydrogen maleate 作用下， 以 水 为溶剂， 以46%的产率得到1,4-bis(2'-chloroethyl)-1,4-diazabicyclo<2.2.1>heptane dihydrogen dimaleate
  参考文献：
  名称：

  Pettit, George R.; Gieschen, Donald P.; Pettit, William E., Canadian Journal of Chemistry, 1981, vol. 59, p. 217 - 221

  摘要：

  DOI：