N,N'-octylenebis(ferrocenylmethylidene)imine | 955030-17-8

• 英文名称: N,N'-octylenebis(ferrocenylmethylidene)imine
• CAS: 955030-17-8
• 化学式: C₃₀H₃₆Fe₂N₂
• 分子量: 536.323
• InChiKey: XBRZNKAFQLVZKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二茂铁甲醛 、 1,8-辛二胺 以 neat (no solvent, solid phase) 为溶剂， 以97%的产率得到N,N'-octylenebis(ferrocenylmethylidene)imine
  参考文献：
  名称：

  Solvent-free synthesis of bisferrocenylimines and their rhodium(I) complexes

  摘要：

  The solvent-free reaction of ferrocenecarboxaldehyde and diaminoalkanes under solvent-free conditions gave bisferrocenylimines (L) in excellent yields Cationic rhodium(I) complexes with the formulation [Rh(COD))(L)]ClO4 were prepared by the reaction of [Rh(COD)Cl](2). with the bisferrocenylimines in the presence of silver perchlorate The compounds were characterised by NMR, IR, MS and elemental analysis The X-ray crystal structures of two rhodium(I) complexes are also reported (C) 2009 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.poly.2009.11.017

文献信息

• Emission switching of ferrocenyl Schiff bases and a representative ruthenium complex in alkaline DMSO: Absorption, electrochemical and microstructural studies
  作者：Lallan Mishra、Santosh Kumar Dubey

  DOI：10.1016/j.saa.2006.12.002

  日期：2007.10

  N,N'-Bis(4-ferrocenyl)-p-phenylene/octamethylene-diimines (L-1/L-2) and a representative Ru(II) complex [Ru(DMSO)(2)Cl2L1]center dot 2H(2)O were prepared and characterized which showed many fold enhancement in their luminescence in alkaline dimethylsulfoxide (DMSO) solution. Spectral and electrochemical properties of these compounds have been studied. Microstructure (SEM) of L-1 and its complex showed single-phase porous material of crystal size similar to 1 mu m. (C) 2006 Elsevier B.V. All rights reserved.