[Ni(μ-1,1-azido)(C5H4NCH2SC6H4NNC6H3(tBu)O)]2 | 1057560-82-3

• 英文名称: [Ni(μ-1,1-azido)(C5H4NCH2SC6H4NNC6H3(tBu)O)]2
• CAS: 1057560-82-3
• 化学式: C₄₄H₄₄N₁₂Ni₂O₂S₂
• 分子量: 954.425
• InChiKey: IVZPPOGLNNRKFL-KUFPYHQXSA-L

反应信息

• 作为产物：
  描述：

  sodium azide 、 nickel(II) nitrate hexahydrate 、 2-(2-pyridylmethylthio)-phenylazo-(4-tert-butyl)phenol 以 甲醇 为溶剂， 生成 [Ni(μ-1,1-azido)(C5H4NCH2SC6H4NNC6H3(tBu)O)]2
  参考文献：
  名称：

  Nickel(II) complexes of tetradentate NSNO pyridylthioazophenol ligands: Synthesis, characterization and crystal structure

  摘要：

  Two sets of nickel(11) complexes of a series of tetradentate NSNO ligands were synthesized and isolated in their pure form. All these complexes, formulated as [Ni(L)Cl](2) and [Ni(L)(N-3)](2) [HL = pyridylthioazophenols], were characterized using physicochemical and spectroscopic tools. The solid-state structures of two complexes (1a and 2a) were established by X-ray crystallography. The geometry about the nickel ion of the complexes is octahedral and the complexes are dimeric in nature. In 1, two Ni(II) ions are bridged by two Cl- anions while in 2 they are bridged by two azide ions in a mu-1,1-bridging fashion. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.04.026