[Re(CO)3(2-(1-phenyl-1H-benzoimidazol-2-yl)phenolate)(pyridine)] | 1264292-03-6

• 英文名称: [Re(CO)3(2-(1-phenyl-1H-benzoimidazol-2-yl)phenolate)(pyridine)]
• CAS: 1264292-03-6
• 化学式: C₂₇H₁₈N₃O₄Re
• 分子量: 634.665
• InChiKey: ZRTSGCHFNPCVQR-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  吡啶 、 [Re2(CO)6(2-(1-phenyl-1H-benzoimidazol-2-yl)phenolate)2] 以 吡啶 为溶剂， 以85%的产率得到[Re(CO)3(2-(1-phenyl-1H-benzoimidazol-2-yl)phenolate)(pyridine)]
  参考文献：
  名称：

  Synthesis, Crystal Structure, and Optical and Photoelectrochemical Properties of a N∩O⁻ Rhenium(I) Complex

  摘要：

  The neutral dimer complex Re-7(CO)(6)(BIZ)(2) was directly obtained from a simple reaction between Re(CO)(5)Cl and N boolean AND OH-type ligand 2(l-phenyl-1H-benzoimidazol-2-yl)phenol (HBIZ). The further reaction of Re-2(CO)(6)(BIZ)(2) with pyridine (Py) led to the monomeric Re(CO)(3)(BIZ)(Py), which was characterized by means of single-crystal X-ray diffraction analysis, H-1 NMR, elemental analysis, and UV-visible absorption, photoluminescence, and infrared spectroscopy as well as cyclic voltammetry. The photoelectrochemical properties of Re(CO)(3)(BIZ)(Py) spin-coated film modified indium-tin oxide electrode were investigated, and a large cathodic photocurrent up to 0.55 mu A/cm(2) at-0.3 V bias potential was observed. The LUMO and HOMO energy levels of Re(CO)(3)(BIZ)(Py) were studied by density functional theory calculations. The possible mechanism of the photocurrent generation was discussed.

  DOI：

  10.1021/om100311b