Ru(η(3)-2-MeC3H4)2(i-Pr2P(CH2)3P-iPr2) | 198547-86-3

• 英文名称: Ru(η(3)-2-MeC3H4)2(i-Pr2P(CH2)3P-iPr2)
• CAS: 198547-86-3
• 化学式: C₂₃H₄₈P₂Ru
• 分子量: 487.652
• InChiKey: ADZUCXTZRWEPLH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II) 、 1,3-二(二异丙基膦酰)丙烷 以 正己烷 为溶剂， 以73%的产率得到Ru(η(3)-2-MeC3H4)2(i-Pr2P(CH2)3P-iPr2)
  参考文献：
  名称：

  The preparation and reactions of (η3-allyl)2Ru[Pr2iP(CH2)nPPr2i] complexes

  摘要：

  The title compounds have been prepared either by reacting (cod)(eta(3)-2-MeC3H4)(2)Ru with the appropriate bisphosphine or Ru((Pr2P)-P-i(CH2)(n)PPr2i)Cl-2 with allylmagnesium chloride. In contrast to the analogous iron compounds, the eta(3)-allyl-Ru compounds react with 1,5-hexadiene to give (eta(5)-1-hexadienyl)RuH complexes irrespective of the length of the methylene chain joining the two P atoms in the bidentate ligand. The eta(3)-C3H5-containing compounds react more selectively than the eta(3)-2-MeC3H4-containing compounds and the product of the reaction of the former with acetic acid has been shown by X-ray crystallography to be the ionic complex [Ru((Pr2PC2H4PPr2i)-P-i)(2)OAc]+OAc-. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00310-0