| 210359-70-9

• CAS: 210359-70-9
• 化学式: I₃Te*I₄In
• 分子量: 1130.75
• InChiKey: BEHUERNZPAPYOY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  indium 、 碲化氢 、 碘 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Crystal Structures of [TeI3][GaI4] and [TeI3][InI4]

  摘要：

  The compounds [TeI3][MI4] (M = Ga, In) were obtained as air sensitive black crystals by the reactions of Te, It and Ga or In in vacuum sealed ampoules. The gallium compound crystallizes in the structural type of [SCl3][AlCl4]: monoclinic system, space group Pc (No. 7), a = 7.211(11), b = 7.2340(9), c = 15.67(2) Angstrom and beta = 102.51(6)degrees. The indium derivative crystallizes in the orthorhombic space group Pna2(1) (No.33), a= 14.752(2), b = 7.1915(6) and c= 23.391(5) Angstrom, with two crystallographically independent formula units per asymmetric unit.The structures consist of tetrahedral GaI4- or InI4- and trigonal pyramidal TeI3+ units. Additionally, in both structures the tellurium atoms establish three weak interactions with iodine atoms of the MI4- units to form a distorted octahedral Te3+3 coordination sphere.

  DOI：

  10.1002/(sici)1521-3749(199806)624:6<999::aid-zaac999>3.0.co;2-e