| 17457-69-1

• CAS: 17457-69-1；19224-88-5；81445-93-4
• 化学式: C₃₆H₃₂N₂O₁₀P₂U
• 分子量: 952.634
• InChiKey: SSCXZTLQTLJVGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 三苯基氧化膦 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  Investigations on synthesis, thermolysis, and coordination chemistry of aminophosphine oxides

  摘要：

  Some aminophosphine oxides (AmPOs), (R-1)(R-2)(R-3)P=O [R-1=R-2=R-3=HNCH2CH=CH2; R-1=R-2=Ph, R-3=HNCH2CH=CH2; R-1=R-2=R-3=HNNMe2; R-1=R-2=Ph, R-3=HNNMe2; R-1=R-2=R-3=NC4H8O; R-1=R2=Ph, R-3=NC4H8O], have been synthesized. The coordination chemistry of these AmPOs is studied with La(III), Th(IV), and U(VI) salts. The products are characterized by various analytical and spectroscopic techniques, and the thermal properties of the ligands and their complexes examined. The TGA data for these compounds show different decomposition temperatures, as well as thermal stability of the metal complexes. Comparisons are made among different ligands on their selective complexing ability towards some chosen metal salts. Mulliken population analysis shows that the basicity of P=O of ligand increases with an increase in the number of P-bonded amino groups.

  DOI：

  10.1080/00958972.2013.806656