(C5Me5)2Sm(μ-Me)2AlMe2 | 115756-73-5

• 英文名称: (C5Me5)2Sm(μ-Me)2AlMe2
• CAS: 115756-73-5
• 化学式: C₂₄H₄₂AlSm
• 分子量: 507.939
• InChiKey: ALZSPNCUERMZER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (C5Me5)2Sm{(μ-Me)AlMe2(μ-Me)}2Sm(C5Me5)2 以 氘代甲苯 为溶剂， 生成 (C5Me5)2Sm(μ-Me)2AlMe2
  参考文献：
  名称：

  Reactivity of trimethylaluminum with (C5Me5)2Sm(THF)2: synthesis, structure, and reactivity of the samarium methyl complexes (C5Me5)2Sm[(.mu.-Me)AlMe2(.mu.-Me)]2Sm(C5Me5)2 and (C5Me5)2SmMe(THF)

  摘要：

  DOI：

  10.1021/ja00227a023

文献信息

• An Ethyl Aluminum Oxide (EAO) Complex with μ-<i>η</i>¹:<i>η</i>²-Ethyl Coordination Derived from a Samarocene Carboxylate and Triethylaluminum
  作者：William J. Evans、Timothy M. Champagne、Joseph W. Ziller

  DOI：10.1021/om050270w

  日期：2005.10.1

  The samarocene carboxylate [(C5Me5)(2)Sm(mu-O2CPh)](2) reacts with AlEt3 to form a mixture of metallocene-stabilized ethylaluminum compounds, including an ethyl aluminum oxide (EAO) complex, [(C5Me5)(2)Sm](2)-[(mu-Et)(4)Al4Et6O2], that displays mu-eta(1):eta(2)-Et coordination similar to that found in [(C5Me5)(2)Sm(mu-Et)(mu-Cl)AlEt2](2) obtained from the reaction between [(C5Me5)(2)Sm(mu-Cl)](3) and AlEt3.