trans-[RhCl2(EtOH)(C6H3-2,6-(CH2PCy2)2)] | 167111-57-1

• 英文名称: trans-[RhCl2(EtOH)(C6H3-2,6-(CH2PCy2)2)]
• CAS: 167111-57-1
• 化学式: C₃₄H₅₇Cl₂OP₂Rh
• 分子量: 717.585
• InChiKey: QSUNZWQWSFYENG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[RhCl2(EtOH)(C6H3-2,6-(CH2PCy2)2)] 以 neat (no solvent) 为溶剂， 生成 [RhCl2(C6H3-2,6-(CH2PCy2)2)]
  参考文献：
  名称：

  Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3

  摘要：

  The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.

  DOI：

  10.1016/0022-328x(94)05361-e
• 作为产物：
  描述：

  乙醇 、 trans-[RhCl2(H2O)(C6H3-2,6-(CH2P(cyclohexyl)2)2)] * propan-2-ol 以 乙醇 为溶剂， 生成 trans-[RhCl2(EtOH)(C6H3-2,6-(CH2PCy2)2)]
  参考文献：
  名称：

  Crystal structures of the solvates trans-[RhCl2(MeOH){C6H3-2,6-(CH2PCy2)2}]. 0.41CH2Cl2 and trans-[RhCl2(EtOH){C6H3-2,6-(CH2PCy2)2}]. H2O. Factors influencing the reactions of C6H4-1,3-(CH2PR2)2 with RhCl3

  摘要：

  The terdentate ligands C6H3-2,6-(CH(2)PCy(2))(2) (PCP: Cy = cyclohexyl) in the octahedral solvento complexes trans-[RhCl2(MeOH)(PCP)] and trans-[RhCl2(EtOH)(PCP)] adopt conformations which minimise the interactions between the sterically demanding Cy groups and the trans chlorides. Comparison of these structures with those of related molecules, including square-pyramidal and square-planar species, suggests an explanation for the different structural types obtained as products from reactions of RhCl3.3H(2)O and various ligands C6H4-1,3-(CH(2)ER(2))(2) with E = N or P.

  DOI：

  10.1016/0022-328x(94)05361-e