[Cp*Ru(1,2-bis(diphenylphosphino)ethane)(MeCN)]PF6 | 92362-03-3

• 英文名称: [Cp*Ru(1,2-bis(diphenylphosphino)ethane)(MeCN)]PF6
• 英文别名: [Cp*Ru(1,2-bis(diphenylphosphino)ethane)(MeCN)]PF₆；[Cp*Ru(dppe)(MeCN)]PF₆；[(η(5)-C5Me5)Ru(1,2-bis(diphenylphosphino)ethane)(MeCN)]PF6
• CAS: 92362-03-3
• 化学式: C₃₈H₄₂NP₂Ru*F₆P
• 分子量: 820.74
• InChiKey: VXWARWULWKCBFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  pentamethyl cyclopentadienyl-η6-naphthalene-ruthenium hexachlorophosphate 、 乙腈 、 1,2-双(二苯基膦)乙烷 反应 12.0h， 以86%的产率得到[Cp*Ru(1,2-bis(diphenylphosphino)ethane)(MeCN)]PF6
  参考文献：
  名称：

  Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+

  摘要：

  The cation [Cp*Ru(C10H8)](+) exchanges naphthalene for various ligands under near-UV (365 nm) or visible light irradiation giving the half-sandwich complexes [Cp*RuL3](+) [L = P(OMe)(3), 1,3,5-triaza-7-phosphaadamantane, (BuNC)-N-t], [Cp*Ru(dppe)(MeCN)](+), Cp*Ru(CO)(2)Cl, Cp*Ru[tris(pyrazol)borate] and [Cp*Ru(C6H6)](+) in 80-95% yields.

  DOI：

  10.1016/j.mencom.2015.01.010

文献信息

• Catalyst Comparison for Additive-Free Acceptorless Dehydro­genation of Indoline Derivatives
  作者：Johanna M. Blacquiere、James M. Stubbs、Amrit S. Nanuwa、Matthew D. Hoffman

  DOI：10.1055/s-0042-1751417

  日期：2023.3

  type [Ru(Cp/Cp*)(P–P)(MeCN)]PF6, bearing cooperative or noncooperative bidentate phosphine ligands, were evaluated for the catalytic acceptorless dehydrogenation of indoline. The systematic comparison revealed that the optimal cooperative catalyst structure included a Cp ancillary ligand, and an N,N-disubstituted P,P-disubstituted 1,5-diaza-3,7-diphosphacyclooctane ligand, denoted as (PR 2NR′ 2). A cooperative

  一组 13 种类型为 [Ru(Cp/Cp*)(P–P)(MeCN)]PF 6的催化剂，带有协同或非协同双齿膦配体，用于二氢吲哚的无受体催化脱氢反应。系统比较表明，最佳协同催化剂结构包括 Cp 辅助配体和N，N-二取代P，P-二取代 1,5-diaza-3,7-二磷环辛烷配体，表示为 (P R 2 N R' 2 ). 轴承 a P Ph 2 N Ph 2的合作复合体配体的寿命比以（二苯基膦）乙烷（dppe）作为支持双膦配体的非合作类似物长两倍。协同催化剂有效地使一系列二氢吲哚底物脱氢，得到取代的吲哚。
• Treichel, P. M.; Komar, D. A.; Vincenti, P. J., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1984, vol. 14, p. 383 - 400
  作者：Treichel, P. M.、Komar, D. A.、Vincenti, P. J.

  DOI：——

  日期：——
• Pentamethylcyclopentadienyl ruthenium(II) complexes containing chiral diphospines: synthesis, characterisation and electrochemical behaviour. X-ray structure of (η5-C5Me5)Ru{(S,S)-Ph2PCH(CH3)CH(CH3)PPh2}Cl
  作者：Franco Morandini、Anna Dondana、Ingrid Munari、Giuseppe Pilloni、Giambattista Consiglio、Angelo Sironi、Massimo Moret

  DOI：10.1016/s0020-1693(98)00219-9

  日期：1998.11

  Some pentamethylcyclopentadienyl ruthenium(II) diphosphine chloride complexes have been prepared by ligand exchange starting with the parent triphenylphosphine derivatives and their reactivities compared with those of the corresponding cyclopentadienyl compounds. The pentamethyl ligand causes a greater extent of asymmetric induction when the (R)-prophos and (R)-phenphos ligands are used as well as a higher lability of the stereochemistry at the stereogenic ruthenium centre. A shift of about 200 mV in the oxidation potential is caused by the substitution at the penta-hapto ligand. The order of basicity of the diphosphine ligands was also evaluated and was found to be consistent with previous determinations. The crystal structure of(eta(5)-C5Me5)Ru (S,S)-chiraphos}Cl shows a coordination around the ruthenium atom similar to that found for the (eta(5)-C5H5)Ru(S,S) -chiraphos}Cl complex. (C) 1998 Elsevier Science S.A. All rights reserved.