| 432004-48-3

• CAS: 432004-48-3
• 化学式: C₂₅H₂₈FeN₃O₂P
• 分子量: 489.337
• InChiKey: MHXQQZCKZIGSOC-KCOFNFEMSA-N

反应信息

• 作为产物：
  描述：

  以 二氯甲烷 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Fumarodinitrile:  A Versatile Reagent in Phosphaalkene and Arsaalkene Chemistry

  摘要：

  Reaction of equimolar amounts of the ferriophosphaalkene Cp*(CO)(2)FeP=C(Ph)NMe2 (1a) and fumarodinitrile in diethyl ether afforded the ferriophosphetane CP*(CO)(2)FeP-CH(CN)-CH(CN)-C(Ph)NMe2 (2a). Analogously, Cp*(CO)(2)FeP=C(tBu)NMe2 (1b) was converted into Cp*(CO)(2)FeP-CH(CN)-CH(CN)-C(tBu)NMe2 (2b). Evidence for the cyclic structure of 2a,b in the crystal was provided by the X-ray structural analysis of 2a. Whereas the phosphetane ring of 2b is retained in solution, product 2a in CH2Cl2 solution underwent an isomerization to give the acyclic secondary ferriophosphane Cp*(CO)(2)Fe-P(H)-CH(CN)-C(CN)=C(Ph)NMe2 (3a) as a mixture of isomers. The ferriophosphane Cp*(CO)(2)FeP[CH(CN)-CH2CN]-[CH(CN)-C(CN)=C(tBu)NMe2] (5) was isolated in less than 1% yield from the reaction of 1b and the alkene. The reaction of ferrioarsaalkene Cp*(CO)(2)FeAs=C(Ph)NMe2 (6) and fumaronitrile gave rise to the formation of the ferrioarsetane Cp*(CO)(2)FeAsCH(CN)-CH-(CN)-C(Ph)NMe2 (7), which unlike 2a resists ring opening in solution.

  DOI：

  10.1021/om010990c