(1-fluoro-2,3-diphenylphosphirene)pentacarbonylmolybdenum | 875057-98-0

• 英文名称: (1-fluoro-2,3-diphenylphosphirene)pentacarbonylmolybdenum
• CAS: 875057-98-0
• 化学式: C₁₉H₁₀FMoO₅P
• 分子量: 464.198
• InChiKey: OQUSDWKVTMNXSQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  7-fluoro-7-phosphanorbornadiene pentacarbonylmolybdenum 、 二苯基乙炔 以 xylene 为溶剂， 以9%的产率得到(1-fluoro-2,3-diphenylphosphirene)pentacarbonylmolybdenum
  参考文献：
  名称：

  Generation and Trapping of a Superelectrophilic Terminal Fluorophosphinidene Complex

  摘要：

  Comparative DFT calculations on terminal phosphinidene complexes [MeP-Cr(CO)(5)] and [FP-Cr(CO)(5)] show a huge increase of the positive charge at P when replacing the methyl by the fluorine substituent (NBO charges +0.60 and +0.94). The electrophilic fluorination of the (3,4-dimethylphospholyl)pentacarbonylmolybdenum anion by Selectfluor gives a straightforward access to the corresponding 1-fluoro-3,4dimethylphosphole molybdenum complex. This complex reacts as a conjugated diene with dimethyl acetylenedicarboxylate to give the corresponding 7-fluoro-7-phosphanorbornadiene complex. This bicyclic species is a precursor of [FP-Mo(CO)(5)] at 120 degrees C in xylene, as shown by trapping reactions with diphenylacetylene and 2,3-dimethylbutadiene.

  DOI：

  10.1021/om050870v