[PdMe(ethylene)(N,N,N',N'-tetramethylethylenediamine)](1+) | 208036-83-3

• 英文名称: [PdMe(ethylene)(N,N,N',N'-tetramethylethylenediamine)](1+)
• CAS: 208036-83-3
• 化学式: C₉H₂₃N₂Pd
• 分子量: 265.715
• InChiKey: DKRYAEYBXUZTEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙烯 、 [PdMe(CD2Cl2)(N,N,N',N'-tetramethylethylenediamine)][BMe(C6F5)3] 以 二氯甲烷-D2 为溶剂， 生成 [PdMe(ethylene)(N,N,N',N'-tetramethylethylenediamine)](1+)
  参考文献：
  名称：

  Nature of the Initiation, Propagation, and Chain Transfer Steps during the Formation of Ethylene Oligomers Catalyzed by PdMe₂(N,N,N‘N‘-tetramethylethylenediamine)/B(C₆F₅)₃

  摘要：

  Reaction of equimolar quantities of PdMe2(Me2NCH2CH2NMe2) and B(C6F5)(3) in the presence of ethylene results in the formation of [PdMe(C2H4)(Me2NCH2CH2NMe2)](+)[BMe(C6F5)(3)](-); the latter catalyzes the oligomerization of ethylene to highly branched products, which are apparently formed via both reversible beta-elimination-reinsertion processes and the incorporation of short chain oligomeric products.

  DOI：

  10.1021/om971060p