[Pd2Cl2(triphenylphosphane)3(κ2N,S:κ1N-4-amino-6-ethyl-1,2,4-triazine-3-thion-5-one(-H))](nitrate) | 1310358-22-5

• 英文名称: [Pd2Cl2(triphenylphosphane)3(κ2N,S:κ1N-4-amino-6-ethyl-1,2,4-triazine-3-thion-5-one(-H))](nitrate)
• CAS: 1310358-22-5
• 化学式: C₅₉H₅₂Cl₂N₄OP₃Pd₂S*NO₃
• 分子量: 1303.83
• InChiKey: WNLIWXYOSZLPGZ-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  4-amino-6-ethyl-1,2,4-triazine-3-thion-5-one 、 silver nitrate 、 三苯基膦 、 palladium dichloride 在 CH₃COONa 作用下， 以 甲醇 、 乙腈 为溶剂， 以85%的产率得到[Pd2Cl2(triphenylphosphane)3(κ2N,S:κ1N-4-amino-6-ethyl-1,2,4-triazine-3-thion-5-one(-H))](nitrate)
  参考文献：
  名称：

  Synthesis, characterization and crystal structures of palladium(II) complexes containing neutral, one and twofold deprotonated 1,2,4-triazine species

  摘要：

  The synthesis and characterization of three new palladium(II) complexes of 4-amino-6-ethyl-1,2,4-triazine-3-thion-5-one (AETTO, H-3 L), [PdCl2(H3L)]center dot H2O (1), [Pd2Cl2(H2L)(PPh3)(3)]NO3 center dot 2CH(3)CN (2) and [Pd(HL)(PPh3)(2)] (3), are reported. All the synthesized compounds are air-stable and were characterized by elemental analyses, IR, NMR spectroscopy and mass spectrometry. In addition, the molecular structures of the complexes have been determined by X-ray single crystal diffraction. On the basis of the crystallographic data, the neutral ligand in 1 and the deprotonated ligands in 2 and 3 act as bidentate NS donors. The singly deprotonated ligand in 2 acts as a bridging agent between two metal centers in the binuclear Pd-II-complex. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.03.048