[Co(6-carboxylato-2-(pyridylmethyl)-bis(2-pyridylmethyl)amine)Cl]ClO4 | 668446-90-0

• 英文名称: [Co(6-carboxylato-2-(pyridylmethyl)-bis(2-pyridylmethyl)amine)Cl]ClO4
• CAS: 668446-90-0
• 化学式: C₁₉H₁₇ClCoN₄O₂*ClO₄
• 分子量: 527.266
• InChiKey: HOSVQDYLMDIYLS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(II) perchlorate hexahydrate 、 [2,6-bis[bis(2-pyridylmethyl)amino]methyl]-pyridine 在 LiClO₄ 作用下， 以 not given 为溶剂， 生成 [Co(6-carboxylato-2-(pyridylmethyl)-bis(2-pyridylmethyl)amine)Cl]ClO4
  参考文献：
  名称：

  An unusual but informative synthesis and the crystal structure of [Co(tpaCO2)Cl](ClO4) (tpaCO2−=6-carboxylato-2- (pyridylmethyl)-bis(2-pyridylmethyl)amine)

  摘要：

  Reaction of 2,6-bis(bis(2-pyridylmethyl)amino)methylpyridine (bpa-tpa) with CO(ClO4)(2).6H(2)O has produced [Co(tpaCO(2)) Cl](ClO4), the first structurally characterised cobalt(III) complex of a ligand based on the tris(2-pyridylmethyl)amine (tpa) skeleton; the formation of tpaCO(2)(-) in the reaction highlights the instability of pyridylmethylamines to oxidative cleavage, which has implications for the long-term stability of catalysts prepared from such ligands. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.08.001