[Cd(1-((benzotriazol-1-yl)methyl)-1H-1,3-imidazole)2Cl2] | 1240302-77-5

• 英文名称: [Cd(1-((benzotriazol-1-yl)methyl)-1H-1,3-imidazole)2Cl2]
• CAS: 1240302-77-5
• 化学式: C₂₀H₁₈CdCl₂N₁₀
• 分子量: 581.746
• InChiKey: ADRCYLYYRJBPID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  aqueous cadmium chloride 、 1-((benzotriazol-1-yl)methyl)-1-H-1,3-imidazole 以 甲醇 为溶剂， 以23%的产率得到[Cd(1-((benzotriazol-1-yl)methyl)-1H-1,3-imidazole)2Cl2]
  参考文献：
  名称：

  Self-assembly of three Cd(II) complexes: From 0-D to 1-D and 2-D structures based on 1-((benzotriazol-1-yl)methyl)-1-H-1,3-imidazole ligand and different anions

  摘要：

  Three new complexes with the formulas [Cd(bmi)(2)I-2] (1), [Cd(bmi)(2)(Cl)(2)](n) (2) and [Cd(bmi)(2)(SCN)(2)](n), (3) have been obtained through the self-assembly of an unsymmetrical ligand 1-((benzotriazol-1-yl)methyl)-1-H-1,3-imidazole (bmi) with Cd(II) salts at room temperature. Single crystal X-ray diffraction determination shows that complex 1 possesses mononuclear structure, complex 2 displays 1-D chain structure constructed by chloride bridging Cd(II) ions, and complex 3 exhibits 2-D grid network structure. In complexes 1 and 2, the unsymmetrical bmi ligands coordinate to metal ions as monodentate mode with the N atom from imidazole ring in preference to the N atom from benzotriazol ring. While in complex 3, bmi ligands coordinate to metal ions as mu(2)-bridging mode with N atoms from imidazole and benzotriazol rings simultaneously. Additionally, their fluorescent properties also have been determined. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2010.03.078