[(PhPH(O)C6H4C3H2NOMe2)Ir(1,5-cyclooctadiene)] | 1256265-91-4

• 英文名称: [(PhPH(O)C6H4C3H2NOMe2)Ir(1,5-cyclooctadiene)]
• 英文别名: [(PhPH(O)C6H4C3H2NOMe2)Ir(COD)]
• CAS: 1256265-91-4
• 化学式: C₂₅H₂₉IrNO₂P
• 分子量: 598.705
• InChiKey: WTYPEZMIRGDLAA-MKAGZSERSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)diiridium(I) dichloride 、 PhPH(O)C6H4C3H2NOMe2 在 NaOH 作用下， 以 甲醇 为溶剂， 生成 [(PhPH(O)C6H4C3H2NOMe2)Ir(1,5-cyclooctadiene)]
  参考文献：
  名称：

  Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage

  摘要：

  Aryl-iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl](2) and secondary phosphine oxide-oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C-P cleavage, was assigned by X-ray analysis and NMR spectroscopy.

  DOI：

  10.1021/om1007874