[PdCl(trimethylphosphine)(2-chlorobenzylidene-2,6-diisopropylphenylamine(-1H))] | 1338077-52-3

• 英文名称: [PdCl(trimethylphosphine)(2-chlorobenzylidene-2,6-diisopropylphenylamine(-1H))]
• CAS: 1338077-52-3
• 化学式: C₂₂H₃₀Cl₂NPPd
• 分子量: 516.787
• InChiKey: LBLCFSRKINTUSB-JIYBLNNWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PdCl(trimethylphosphine)(2-chlorobenzylidene-2,6-diisopropylphenylamine(-1H))] 、 四(3,5-二(三氟甲基)苯基)硼酸钠 、 乙腈 以 二氯甲烷 、 乙腈 为溶剂， 以90%的产率得到[Pd(acetonitrile)(trimethylphosphine)(2-chlorobenzylidene-2,6-diisopropylphenylamine(-1H))][B(3,5-bistrifluoromethylphenyl)4]
  参考文献：
  名称：

  Cationic palladacycles as catalyst precursors for phenyl acetylene polymerization

  摘要：

  Novel cationic palladacycles based on benzylidene-2,6-diisopropylphenylimines were prepared via C-H activation using Pd(CH(3)CN)(2)Cl(2) as metal precursor. The complexes were fully characterized by IR and NMR spectroscopy, mass spectrometry and elemental analysis. The cationic palladacycles were found to be active catalysts for the polymerization of phenylacetylene producing largely trans-cisoidal PPA. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.07.044
• 作为产物：
  描述：

  2-chlorobenzylidene-2,6-diisopropylphenylamine 在 sodium acetate 作用下， 以 二氯甲烷 为溶剂， 生成 [PdCl(trimethylphosphine)(2-chlorobenzylidene-2,6-diisopropylphenylamine(-1H))]
  参考文献：
  名称：

  Cationic palladacycles as catalyst precursors for phenyl acetylene polymerization

  摘要：

  Novel cationic palladacycles based on benzylidene-2,6-diisopropylphenylimines were prepared via C-H activation using Pd(CH(3)CN)(2)Cl(2) as metal precursor. The complexes were fully characterized by IR and NMR spectroscopy, mass spectrometry and elemental analysis. The cationic palladacycles were found to be active catalysts for the polymerization of phenylacetylene producing largely trans-cisoidal PPA. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.07.044