| 1426913-20-3

• CAS: 1426913-20-3
• 化学式: C₈₁H₇₃N₄O₁₈P
• 分子量: 1421.46
• InChiKey: BTYUOIISHBEMFM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrole 在 吡啶 、 三氯氧磷 、 水 、 silica gel 作用下， 以 正己烷 、 乙酸乙酯 为溶剂， 反应 1.5h， 以36%的产率得到
  参考文献：
  名称：

  Aluminum, Gallium, Germanium, Copper, and Phosphorus Complexes of meso-Triaryltetrabenzocorrole

  摘要：

  5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV-vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the pi-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.

  DOI：

  10.1021/ic400162y