| 198711-25-0

• CAS: 198711-25-0
• 化学式: C₃₂H₃₀AuClN₂P*Cl
• 分子量: 741.45
• InChiKey: OYOXCYRTSUGDFE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-苯胺基吡啶 以 二氯甲烷 、 水 为溶剂， 生成
  参考文献：
  名称：

  Direct cycloauration of 2-anilinopyridine (Hanp) with tetrachloroaurate(III) and the X-ray crystal structure of [AuCl2(anp)]

  摘要：

  2-Anilinopyridine (Hanp) reacted with sodium tetrachloroaurate(III) in refluxing water directly to give cyclometallated [AuCl2(anp)], which was characterized spectroscopically and its structure determined by X-ray analysis. The metallation reaction involved direct activation of an ortho C-H bond of the phenyl moiety and the deprotonated anionic ligand, anp, coordinated to Au through-the pyridine-N and phenyl ortho-C atoms forming a six-membered chelate ring. Similarly cycloaurated complexes, [AuBr2(anp)] and [AuCl2(C-N)] (CN = tlp, map, and tpm), were also prepared and characterized (Htlp = 2-(p-toluidino)pyridine, Hmap = 2-(N-methylanilino)pyridine, and Htpm = 2-(p-toluidino)pyrimidine). (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00176-9