dichlorobis(3,5-dimethylpyrazole-N(2))-methylphenyltin(IV) | 292825-96-8

• 英文名称: dichlorobis(3,5-dimethylpyrazole-N(2))-methylphenyltin(IV)
• CAS: 292825-96-8
• 化学式: C₁₇H₂₄Cl₂N₄Sn
• 分子量: 474.02
• InChiKey: MOLZNHXPYVEGCX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 methylphenyltin(IV) dichloride 以 氯仿 为溶剂， 生成 dichlorobis(3,5-dimethylpyrazole-N(2))-methylphenyltin(IV)
  参考文献：
  名称：

  Dichlorobis(3,5-dimethylpyrazole-N²)methylphenyltin(IV)

  摘要：

  The title compound, [SnCl2 (CH3)(C6H5)(C5H8N2)(2)], was obtained by reaction of dichloromethylphenyltin(IV) and 3,5-dimethylpyrazole (dmpz) in chloroform, and was recrystallized from acetone. The structure consists of octahedral all-trans [SnMePhCl2 (dmpz)(2)] molecules, with the Sn atom coordinated to two C [Sn-C 2.127 (5) and 2.135 (4) Angstrom], two Cl [Sn-Cl 2.5753 (8) Angstrom] and two N atoms [Sn-N 2.357 (3) Angstrom]. The dmpz ligands, bound to the metal through their unprotonated N atoms, form weak intra- and intermolecular hydrogen bonds with the Cl ligands via their NH groups, giving rise to a polymeric chain along the c axis.

  DOI：

  10.1107/s0108270100007058