| 490023-95-5

• CAS: 490023-95-5
• 化学式: C₂₇H₃₂U
• 分子量: 594.58
• InChiKey: VGESVHDQBVQPLI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Tribenzyl(pentamethylcyclopentadienyl)uranium 、 环戊二烯 以 甲苯 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Convenient Synthesis, Structure, and Reactivity of (C₅Me₅)U(CH₂C₆H₅)₃:  A Simple Strategy for the Preparation of Monopentamethylcyclopentadienyl Uranium(IV) Complexes

  摘要：

  A high-yield one-pot synthesis of (C5Me5)U(CH2C6H5)(3) has been developed and applied to the synthesis of a new organouranium complex possessing a (pentamethyleyelopentadienyl)bis(cyclopentadienyl) ligand framework, (C5Me5)(C5H5)(2)U(CH2C6H5). Both complexes have been structurally characterized. We also report herein an improved and safer synthesis for the popular uranium starting material UCl4.

  DOI：

  10.1021/om0206610