Zr(Me2Si(η-C5H4)2)(η-C5H5)Cl | 179400-07-8

• 英文名称: Zr(Me2Si(η-C5H4)2)(η-C5H5)Cl
• CAS: 179400-07-8
• 化学式: C₁₇H₁₉ClSiZr
• 分子量: 378.1
• InChiKey: JPSCSEPICBRXOZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Zr(Me2Si(η-C5H4)2)(η-C5H5)Cl 、 (η⁵-cyclopentadienyl)trichlorohafnium dimethoxyethane 以 甲苯 为溶剂， 以52.7%的产率得到(η-C5H5)ZrCl2(μ-η-C5H4-(SiMe2)-η-C5H4)HfCl2(η-C5H5)
  参考文献：
  名称：

  Synthesis and catalytic properties of ansa-binuclear metallocenes of the Group IV transition metals

  摘要：

  The new ansa-bridged mono- and bi-nuclear Group IV metallocenes, {Zr[X(eta-C5H4)(2)](eta-C5H5)Cl} (where, X = SiMe(2) (1), CMe(2)CMe(2) (2)), {[(eta-C5H5)HfCl2][mu-eta-C5H4-(SiMe(2))-eta-C5H4][(eta-C5H5)HfCl2]} (3). {[(eta-C5H5)ZrCl2][mu-eta-C5H4(SiMe(2)CH(2)CH(2)SiMe(2))-eta-C5H4][(eta-C5H5)ZrCl2]} (4), {[(eta-C5H5)ZrCl2][mu-eta-C5H4-(SiMe(2))-eta-C9H6][(eta-C5H5)ZrCl2]} (5), {[(eta-C5H5)ZrCl2][mu-eta-C9H6-(SiMe(2))-eta-C9H6][(eta-C5H5)ZrCl2]} (6), {[(eta-C5H5)ZrCl2][mu-eta-C5H4-(SiMe(2))-eta-C5H4][(eta-C5H5)MCl(2)]}, M = Hf (7) or Ti (8), {[(eta-C5H5)ZrCl2][mu-eta-C5H4-(SiMe(2))-eta-C5H4][(eta-C(5)Me(5))TiCl2]} (9) and {[(eta-C5H5)ZrCl2][mu-eta-C5H4(SiMe(2))-eta-C5H4][TiCl3]} (10) an described. These compounds in the presence of methylaluminoxane are catalysts for the polymerisation of ethene and propene.

  DOI：

  10.1016/0022-328x(96)06198-0
• 作为产物：
  描述：

  (η5-cyclopentadienyl)trichlorozirconium dimethoxyethane 、 dimethylsilanediylbis(cyclopentadienylmethyl) dilithium salt 以 甲苯 为溶剂， 以20.1%的产率得到Zr(Me2Si(η-C5H4)2)(η-C5H5)Cl
  参考文献：
  名称：

  Synthesis and catalytic properties of ansa-binuclear metallocenes of the Group IV transition metals

  摘要：

  The new ansa-bridged mono- and bi-nuclear Group IV metallocenes, {Zr[X(eta-C5H4)(2)](eta-C5H5)Cl} (where, X = SiMe(2) (1), CMe(2)CMe(2) (2)), {[(eta-C5H5)HfCl2][mu-eta-C5H4-(SiMe(2))-eta-C5H4][(eta-C5H5)HfCl2]} (3). {[(eta-C5H5)ZrCl2][mu-eta-C5H4(SiMe(2)CH(2)CH(2)SiMe(2))-eta-C5H4][(eta-C5H5)ZrCl2]} (4), {[(eta-C5H5)ZrCl2][mu-eta-C5H4-(SiMe(2))-eta-C9H6][(eta-C5H5)ZrCl2]} (5), {[(eta-C5H5)ZrCl2][mu-eta-C9H6-(SiMe(2))-eta-C9H6][(eta-C5H5)ZrCl2]} (6), {[(eta-C5H5)ZrCl2][mu-eta-C5H4-(SiMe(2))-eta-C5H4][(eta-C5H5)MCl(2)]}, M = Hf (7) or Ti (8), {[(eta-C5H5)ZrCl2][mu-eta-C5H4-(SiMe(2))-eta-C5H4][(eta-C(5)Me(5))TiCl2]} (9) and {[(eta-C5H5)ZrCl2][mu-eta-C5H4(SiMe(2))-eta-C5H4][TiCl3]} (10) an described. These compounds in the presence of methylaluminoxane are catalysts for the polymerisation of ethene and propene.

  DOI：

  10.1016/0022-328x(96)06198-0