[Cu2(tidf)(H2O)2]Ni(CN)4 | 1320208-13-6

• 英文名称: [Cu2(tidf)(H2O)2]Ni(CN)4
• CAS: 1320208-13-6
• 化学式: C₄N₄Ni*C₂₄H₃₀Cu₂N₄O₄
• 分子量: 728.379
• InChiKey: VZCFVMQYQDUULD-OMUIZLMBSA-L

反应信息

• 作为产物：
  描述：

  potassium tetracyanidonickellate(II) monohydrate 、 Cu2(tidf)(ClO4)2(H2O)2 以 水 、 异丙醇 、 乙腈 为溶剂， 以96%的产率得到[Cu2(tidf)(H2O)2]Ni(CN)4
  参考文献：
  名称：

  Supramolecular assembly of new heteropolymetalic molecules based on tetraiminodiphenolate macrocycle and hexacyanometallate anions: Magnetostructural and spectroscopic properties

  摘要：

  Herein we report on the synthesis, single crystal X-ray structure, spectroscopic and magnetic properties of [{Cu-2(tidf)(H2O)}(2)(mu-CN)(2)Fe(CN)(4)]center dot 6H(2)O (1), [Cu-2(tidf)(H2O)2][Ni(CN)(4)] (2) and [Cu-2(tidf)(H2O)(2)][Fe(CN)(5)NO]center dot H2O (3) (tidf = a Robson type macrocyclic ligand obtained on condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). Complex (1) is pentanuclear; two paramagnetic dicopper(II) units are linked by a hexacyanoferrate(II) ion through two cyano-bridges. All compounds exhibit extensive, three-dimensional, supramolecular structures supported by classic hydrogen bonding between the coordinated aqua ligands, water molecules and cyano groups. Magnetism as a function of the temperature of complexes 1-3 is consistent with a strong antiferromagnetism with exchange parameters 2J estimated -783(29), -913(2), -905(1), respectively. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.05.001