[Zn2(salicylaldehyde semicarbazone(-H))2(acetate)2] | 1285541-23-2

• 英文名称: [Zn2(salicylaldehyde semicarbazone(-H))2(acetate)2]
• CAS: 1285541-23-2
• 化学式: C₂₀H₂₂N₆O₈Zn₂
• 分子量: 605.21
• InChiKey: NEEASSALHPCQPA-KHFPQQQUSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc diacetate 、 salicylaldehyde semicarbazone 以 甲醇 为溶剂， 以54%的产率得到[Zn2(salicylaldehyde semicarbazone(-H))2(acetate)2]
  参考文献：
  名称：

  Binuclear zinc(II) complexes with the anti-inflammatory compounds salicylaldehyde semicarbazone and salicylaldehyde-4-chlorobenzoyl hydrazone (H2LASSBio-1064)

  摘要：

  Complexes [Zn-2(HL1)(2)(CH3COO)(2)] (1) and [Zn-2(L-2)(2)] (2) were synthesized with salicylaldehyde semicarbazone (H2L1) and salicylaldehyde-4-chlorobenzoyl hydrazone (H(2)LASSBio-1064, H2L2), respectively. The crystal structure of (1) was determined. Upon recrystallization of previously prepared [Zn-2(HL2)(2)(Cl)(2)] (3) in 1:9 DMSO:acetone crystals of [Zn-2(L-2)(2)(H2O)(2)]center dot[Zn-2(L-2)(2)(DMSO)(4)] (3a) were obtained. The crystal structure of 3a was also determined. All crystal structures revealed the presence of phenoxo-bridged binuclear zinc(II) complexes. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.04.024