| 754982-55-3

• CAS: 754982-55-3
• 化学式: C₅₂H₄₂Co₂N₆O₁₀S₂*H₂O
• 分子量: 1111.07
• InChiKey: KCSHBTWKKOFUBW-DRMHDFJUSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 cobalt(II,III) oxide
  参考文献：
  名称：

  A New Heterocyclic Schiff Base and Its Metal Complexes

  摘要：

  Cu(II), Co(H), Ni(II), and Zn(II) metal complexes of a new SNO tridentate heterocyclic Schiff base derived from the reaction of 1-amino-5benzoyl-4-phenyl-IH-pyfimidine-2-thione with salicylaldehyde have been synthesized and characterized on the basis of elemental analyses, electronic, IR, and H-1 NMR spectra, and also by molar conductivity measurements, magnetic moment measurements and thermogravimetric analyses (TGA). It has been found that the Schiff base behaves as a neutral tridentate SNO ligand forming chelates with I : 2 or I : I (metal: ligand) stoichiometry. The complexes of Co(II), Ni(II), and Zn(II) are proposed to have an octahedral structure, while the Cu(II) complex is suggested to have a square-pyramidal geometry. All of the complexes show nonelectrolytic behavior.

  DOI：

  10.1081/sim-120030436
• 作为产物：
  描述：

  (1-((2-hydroxybenzylidene)amino)-4-phenyl-2-thioxo-1,2-dihydropyrimidin-5-yl)(phenyl)methanone 、 水 、 cobalt(II) diacetate tetrahydrate 以 甲醇 、 氯仿 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  A New Heterocyclic Schiff Base and Its Metal Complexes

  摘要：

  Cu(II), Co(H), Ni(II), and Zn(II) metal complexes of a new SNO tridentate heterocyclic Schiff base derived from the reaction of 1-amino-5benzoyl-4-phenyl-IH-pyfimidine-2-thione with salicylaldehyde have been synthesized and characterized on the basis of elemental analyses, electronic, IR, and H-1 NMR spectra, and also by molar conductivity measurements, magnetic moment measurements and thermogravimetric analyses (TGA). It has been found that the Schiff base behaves as a neutral tridentate SNO ligand forming chelates with I : 2 or I : I (metal: ligand) stoichiometry. The complexes of Co(II), Ni(II), and Zn(II) are proposed to have an octahedral structure, while the Cu(II) complex is suggested to have a square-pyramidal geometry. All of the complexes show nonelectrolytic behavior.

  DOI：

  10.1081/sim-120030436