dibromodichloroborate | 36500-75-1

• 英文名称: dibromodichloroborate
• CAS: 36500-75-1
• 化学式: BBr₂Cl₂
• 分子量: 241.525
• InChiKey: FWLDCSVXXAWHJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.69
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  tetrachloroborate(1-) 、 tetrabromo borate 以 二氯甲烷 为溶剂， 生成 Bromo(trichloro)boranuide 、 dibromodichloroborate 、
  参考文献：
  名称：

  Mixed tetrahaloborate ions. Detection and study by nuclear magnetic resonance

  摘要：

  DOI：

  10.1021/ic50111a005

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.10, 4.4, page 214 - 216
  作者：

  DOI：——

  日期：——
• Solids containing methylhalophosphonium cations [(CH3)n PX+4−n] (n = 1–3 XCl,Br): an investigation using magic-angle spinning NMR spectroscopy
  作者：Robin K. Harris、Andrew Root、Peter N. Gates、Alan S. Muir

  DOI：10.1016/0584-8539(92)80143-k

  日期：1992.10

  A selection of complexes containing [(CH3)nPX4-n+] cations (X = Cl, Br) have been investigated by magic-angle spinning (MAS) P-31 and B-11 NMR spectroscopy. Qualitative information about ionic motion in these systems is derived from the observed linewidths, which are dependent upon the nature of the anions present in the lattices. Isomers of [(CH3)PCl3+Cl-] and [(CH3)2PCl2+Cl-] are detected, confirming previous Raman spectroscopic observations. The mixed-halogen cations [(CH3)PCl2Br+], [(CH3)PClBr2+] and [(CH3)2PClBr+] are also observed, complexed with both single-halide and polyatomic anions. Differences in NMR linewidths are again noted. These results are compared with Raman studies on the same complexes and contrasted with a similar investigation of the [PClnBr4+-n] (0 less-than-or-equal-to n less-than-or-equal-to 4) system.