(η6-cymene)(1-(2-methylpyridine)-2,5-diphenylphosphole)dichlororuthenium | 525579-81-1

• 英文名称: (η6-cymene)(1-(2-methylpyridine)-2,5-diphenylphosphole)dichlororuthenium
• CAS: 525579-81-1
• 化学式: C₃₂H₃₂Cl₂NPRu
• 分子量: 633.563
• InChiKey: BBJBQCOZIQHYDX-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  silver tetrafluoroborate 、 (η6-cymene)(1-(2-methylpyridine)-2,5-diphenylphosphole)dichlororuthenium 以 not given 为溶剂， 以99%的产率得到(η6-cymene)(1-(2-methylpyridine)-2,5-diphenylphosphole)chlororuthenium(II) tetrfluoroborate
  参考文献：
  名称：

  A Cationic 1-(2-Methylpyridine)Phosphole Cymene Ruthenium Chloride Complex as an Efficient Catalyst in the Transfer Hydrogenation of Ketones

  摘要：

  Reaction of 2,5-diphenylphospholide anion with 2-chloromethylpyridine affords the 1-(2-methylpyridine)phosphole ligand. The corresponding cationic Ru-(cymene)Cl chelate complex catalyzes the hydrogen transfer process of ketones with very high TON and TOF numbers.

  DOI：

  10.1021/om030065l
• 作为产物：
  描述：

  dichloro(p-cymene)ruthenium(II) dimer 、 1-(2-methylpyridine)-2,5-diphenylphosphole 以 二氯甲烷 为溶剂， 生成 (η6-cymene)(1-(2-methylpyridine)-2,5-diphenylphosphole)dichlororuthenium
  参考文献：
  名称：

  A Cationic 1-(2-Methylpyridine)Phosphole Cymene Ruthenium Chloride Complex as an Efficient Catalyst in the Transfer Hydrogenation of Ketones

  摘要：

  Reaction of 2,5-diphenylphospholide anion with 2-chloromethylpyridine affords the 1-(2-methylpyridine)phosphole ligand. The corresponding cationic Ru-(cymene)Cl chelate complex catalyzes the hydrogen transfer process of ketones with very high TON and TOF numbers.

  DOI：

  10.1021/om030065l