[(1,5-cyclooctadiene)Rh(o-(C6H5)2PNHC6H4P(S)(C6H5)2-κ2-P,S)](ClO4) | 529488-79-7

• 英文名称: [(1,5-cyclooctadiene)Rh(o-(C6H5)2PNHC6H4P(S)(C6H5)2-κ2-P,S)](ClO4)
• CAS: 529488-79-7
• 化学式: C₃₈H₃₇NP₂RhS*ClO₄
• 分子量: 804.088
• InChiKey: BYUAODUVIVLOEQ-ONEVTFJLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(1,5-cyclooctadiene)RhCl(o-(C6H5)2PNHC6H4P(S)(C6H5)2-P)] 、 silver perchlorate 以 二氯甲烷 为溶剂， 以96%的产率得到[(1,5-cyclooctadiene)Rh(o-(C6H5)2PNHC6H4P(S)(C6H5)2-κ2-P,S)](ClO4)
  参考文献：
  名称：

  Coordination chemistry of o-Ph2PNHC6H4P(S)Ph2 a P,S-donor ligand: synthesis of new Ru, Rh and Ir complexes

  摘要：

  The late transition metal complexes [(Ar)RuCl2(PS)] (Ar=C6H6, o-MeC6H4(Pr-i) and C6Me6), [RuCl2(eta(3):eta(3)-C10H16)(PS)], [RhCl(cod)(PS)] (cod = 1,5-cyclooctadiene) and [(CP*)MCl2(PS)] (Cp* = pentamethylcyclopentadienyl, M = Rh or It) (where. PS = Ph2PNHC6H4P(S)Ph-2) have been synthesised by the reaction of Ph2PNHC6H4P(S)Ph-2 with the appropriate chloride bridged transition metal dimers. In all of these complexes the ligand is monodentate P-bound. Chloride abstraction from representative complexes, using Ag[ClO4], gave the cationic compounds [(o-MeC6H4{Pr-i})RuCl(PS)][ClO4], [Rh(cod)(PS)][ClO4] and [(Cp*)RhC](PS)[ClO4] in which the ligand is k(2)-P,S bound. All new compounds were characterised by a combination of P-31{H-1} and H-1 NMR spectroscopy, microanalysis, FAB mass spectrometry and IR spectroscopy. The molecular structures of five complexes have been determined by single-crystal X-ray diffraction-both monodentate and chelate coordination has been characterised. The P-monodentate compounds all display intramolecular N-H...S hydrogen bonding. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01357-8