[Zn(4,4'-di(3-methyl)pyridyl sulfide)Cl2] | 503270-22-2

• 英文名称: [Zn(4,4'-di(3-methyl)pyridyl sulfide)Cl2]
• CAS: 503270-22-2
• 化学式: C₁₂H₁₂Cl₂N₂SZn
• 分子量: 352.603
• InChiKey: VBQOODXDVJISRZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,4'-di(3-methyl)pyridyl sulfide 、 zinc(II) chloride 以 乙醇 、 氯仿 、 水 为溶剂， 以60%的产率得到[Zn(4,4'-di(3-methyl)pyridyl sulfide)Cl2]
  参考文献：
  名称：

  Crystal structures and physico-chemical properties of two new one-dimensional zinc(II) complexes with sulfide bridging bispyridines

  摘要：

  4,4'-Dipyridyl sulfide (L-1) and 4,4'-di(3-methyl)pyridyl (L-2) sulfide coordination compounds of the general formula Zn(L)(X)(2) (L-1 = 4,4'-dipyridyl sulfide; L-2 = 4,4'-di(3-methyl)pyridyl sulfide; X = CH3COO-, Cl-), have been obtained. The compounds were characterized by single crystal X-ray diffraction, elemental analysis, IR and H-1 NMR. Both compounds are of one-dimensional coordination polymers and crystallize in the orthorhombic systems, while in different space groups with Pnc2 for [ZnL1(CH3COO)(2)] 1 and Pna2(1) for [ZnL2Cl2] 2, respectively. X-ray analysis and H-1 NMR experiments indicate that variation of ligands rather than counter anions, CH3COO- and Cl-, leads to the change in the, modes of the dimensionality array, that is, complexes 1 prefers a linear coordination fashion while complexes 2 exhibits a zigzag conformation. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00446-5