| 1438417-14-1

• CAS: 1438417-14-1
• 化学式: C₃₂H₁₂BF₂₄*C₄₁H₄₆N₂O₃ReS
• 分子量: 1696.32
• InChiKey: YXYNPHARCRPFOB-ZBJMQJRBSA-N

反应信息

• 作为反应物：
  描述：

  在 双(三甲基硅烷基)氨基钾 作用下， 以 甲苯 为溶剂， 以58.6%的产率得到
  参考文献：
  名称：

  Intramolecular Nucleophilic Addition to the 2 Position of Coordinated 2,2′-Bipyridine by a Deprotonated Dimethyl Sulfide Ligand

  摘要：

  Deprotonation of the dimethyl sulfide ligand in [Re(bipy)(CO)(3)(SMe2)][OTf] (1) by KN(SiMe3)(2) afforded a mixture of two diastereomers (2M and 2m) in which a C-C bond has been formed between the S-bonded CH2 group and the 2 position of 2,2'-bipyridine. The solid-state structure of the more stable 2,6-Pr-i-BIAN analogue could be determined by X-ray diffraction.

  DOI：

  10.1021/ic401065h
• 作为产物：
  描述：

  二甲基硫 、 [Re(2,6-iPr-BIAN)(CO)₃(OTf)] 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 二氯甲烷 为溶剂， 反应 2.0h， 以0.1572 g的产率得到
  参考文献：
  名称：

  Intramolecular Nucleophilic Addition to the 2 Position of Coordinated 2,2′-Bipyridine by a Deprotonated Dimethyl Sulfide Ligand

  摘要：

  Deprotonation of the dimethyl sulfide ligand in [Re(bipy)(CO)(3)(SMe2)][OTf] (1) by KN(SiMe3)(2) afforded a mixture of two diastereomers (2M and 2m) in which a C-C bond has been formed between the S-bonded CH2 group and the 2 position of 2,2'-bipyridine. The solid-state structure of the more stable 2,6-Pr-i-BIAN analogue could be determined by X-ray diffraction.

  DOI：

  10.1021/ic401065h