2-(1-(2,6-diisopropylphenylimino)ethylidene)quinolyliron dichloride | 1319733-75-9

• 英文名称: 2-(1-(2,6-diisopropylphenylimino)ethylidene)quinolyliron dichloride
• CAS: 1319733-75-9
• 化学式: C₂₃H₂₆Cl₂FeN₂
• 分子量: 457.226
• InChiKey: XULRRZBEBTXNCF-GJWQCUAUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  iron(II) chloride tetrahydrate 、 2-(1-(2,6-diisopropylphenylimino)ethylidene)quinoline 以 乙醇 为溶剂， 以91%的产率得到2-(1-(2,6-diisopropylphenylimino)ethylidene)quinolyliron dichloride
  参考文献：
  名称：

  Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines

  摘要：

  A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N boolean AND N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl(2), cobalt(II) (Co1-Co5) and iron(II) (Fe1-Fe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3 center dot DMF and Fe4 center dot DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 x 10(6) g mol(-1) (Co) h(-1) and 5.89 x 10(5) g mol(-1) (Fe) h(-1), respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.003