[μ-(CdBr(N3,N7-ethylenediamine-N9-ethyladenine))2CdBr4)] | 909022-68-0

• 英文名称: [μ-(CdBr(N3,N7-ethylenediamine-N9-ethyladenine))2CdBr4)]
• CAS: 909022-68-0
• 化学式: C₁₈H₃₀Br₆Cd₃N₁₄
• 分子量: 1259.18
• InChiKey: PILWMUMIZNZUKY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cadmium(II) bromide 、 9-[2-(2-aminoethylamino)ethyl]adenine hydrochloride 以 水 为溶剂， 生成 [μ-(CdBr(N3,N7-ethylenediamine-N9-ethyladenine))2CdBr4)]
  参考文献：
  名称：

  Conserved supramolecular architecture in polymetallic nucleobase complexes

  摘要：

  The single crystal X-ray structures of two different polynuclear metal-nucleobase complexes are reported. Crystals isolated from the reaction of CdBr2 with ethylenediamine-N9-ethyladenine, A-Et-en, were characterised by X-ray structural analysis as a coordination polymer [mu-{CdBr(N3,N7-A-Et-en)}(2)CdBr4] (2). Reaction of the Pd(II)-adenine complex, [PdCl(N3-A-Et-en)](+), with sodium uracilate yielded [(Pd(N3-A-Et-en)(2)(N1,N3-U)][ClO4](2) (3). Despite the considerable differences in the nature of the compounds the crystal structures feature essentially similar supramolecular architectures. A building block analysis demonstrates how this arises and reveals an approach, based on bond-type substitution and molecular replacement, to conserving such features. This may be a useful approach that could be more widely adopted in crystal engineering strategies. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.01.009