ZnCl2(N,N'-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene) | 1103830-11-0

• 英文名称: ZnCl2(N,N'-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene)
• CAS: 1103830-11-0
• 化学式: C₂₂H₁₆Cl₂N₄Zn
• 分子量: 472.692
• InChiKey: QLOZAMNOSXNNHL-OXBZONAHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene 、 zinc(II) chloride 以 甲醇 为溶剂， 以61%的产率得到ZnCl2(N,N'-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene)
  参考文献：
  名称：

  Synthesis and spectroscopic studies on complexes of N,N’-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene (L); DNA binding studies on Cu(II) complex

  摘要：

  The Schiff base ligand. N.N'-bis-(2-pyridinecarboxaldimine)-1,8-diaminonaphthalene (L), obtained by the condensation of 2-pyridinecarboxaldehyde and 1.8-diaminonaphthalene, has been used to synthesize the mononuclear complexes of the type [MLCl2] [M = Co(II), Ni(II). Cu(II) and Zn(II)]. The newly synthesized ligand (L) and its complexes have been characterized on the basis of results of elemental analysis, molar conductance, magnetic susceptibility measurements, job's method and spectroscopic studies viz., FT-IR, Mass, H-1 and C-13 NMR. The UV-vis and magnetic moment data revealed an octahedral geometry around Co(II), Ni(II) and Cu(II) ions and conductivity data show a non-electrolytic nature of the complexes. Absorption and fluorescence spectroscopic Studies support that Cu(II) complex exhibits significant binding to calf thymus DNA. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2008.07.002