| 408357-63-1

• CAS: 408357-63-1
• 化学式: C₇₂H₆₀Cl₄O₆P₂Ru₂S
• 分子量: 1459.23
• InChiKey: JFSBBHPLOBEULG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 13-[4-[4-(12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yloxy)phenyl]sulfanylphenoxy]-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 以 二氯甲烷 、 苯 为溶剂， 以89.6%的产率得到
  参考文献：
  名称：

  Synthesis of Ru–Arene complexes of Me-Duphos. X-ray, PGSE NMR diffusion and catalytic studies

  摘要：

  Cationic [RuCl(arene)(Me-Duphos)]Cl complexes, arene = eta(6)-benzene and eta(6)-p-cymene, Me-Duphos = 1,2-bis-((2R,5R)-2,5-dimethylphospholano) benzene) have been prepared and studied by X-ray crystallography and NMR spectroscopy. PGSE NMR diffusion studies have been used to recognize (a) ion pairing as a function of solvent and (b) larger molecular volumes. Several arene-Ru-complexes have been shown to be useful catalyst precursors in the hydrolysis of terminal aryl alkynes to afford acetophenones. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00680-6