[Cp*Ru(η3-CHC(CHCH2NP(i-Pr)2)2CPh2-κ4-P,C,C',C'')] | 1059196-30-3

• 英文名称: [Cp*Ru(η3-CHC(CHCH2NP(i-Pr)2)2CPh2-κ4-P,C,C',C'')]
• CAS: 1059196-30-3
• 化学式: C₃₉H₅₈N₂P₂Ru
• 分子量: 717.92
• InChiKey: AZOSIWMQFKDSHR-QDSLRZTOSA-N

反应信息

• 作为产物：
  描述：

  在 KOH or KOC(CH₃)3 作用下， 生成 [Cp*Ru(η3-CHC(CHCH2NP(i-Pr)2)2CPh2-κ4-P,C,C',C'')]
  参考文献：
  名称：

  Formation of a Coordinated 2-Aminoethylidene Ligand and Its Rearrangement by Deprotonation into a Phosphinoallyl Ligand Containing a Pyrrolidin-2-yl Ring

  摘要：

  The activation of 1,1-diphenyl-2-propyn-1-ol by the metallic fragment [(eta(5)-C5Me5)Ru(dippae)](+) {dippae = 1,2-bis[(diisopropylphosphanyl)amino]ethane}, followed by dehydration, produces a cationic complex that, by deprotonation and rearrangement, leads to a neutral complex with a phosphinoallyl ligand containing a pyrrolidin2-yl ring.

  DOI：

  10.1021/ic801302z