(η5-C5H5)Mn(CO)2(η2-cyclopentadiene) | 61384-71-2

• 英文名称: (η5-C5H5)Mn(CO)2(η2-cyclopentadiene)
• CAS: 61384-71-2
• 化学式: C₁₂H₁₁MnO₂
• 分子量: 242.156
• InChiKey: OISQKBPNKQMTDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三羰基(η-环戊二烯基)合锰 、 环戊二烯 以 further solvent(s) 为溶剂， 生成 (η5-C5H5)Mn(CO)2(η2-cyclopentadiene)
  参考文献：
  名称：

  Hydrogen Generation from Water upon CpMn(CO)₃ Irradiation in a Hexane/Water Biphasic System

  摘要：

  Photolysis of CpMn(CO)(3) in a hexane/water biphasic system has been shown to generate hydrogen peroxide and hydrogen in 40-50% yield. Photolysis of the title compound results in loss of a CO ligand followed by coordination of a water molecule. The initially formed CpMn(CO)(2)(H2O) intermediate was detected using time-resolved IR spectroscopy. The cyclopentadiene (CpH) monomer is generated as the major product, formed by the transfer of an H atom from the coordinated H2O solvent to the Cp ring. A simple mechanism for H-2 generation is proposed on the basis of deuteration studies which demonstrate the production of D-2 and CpD upon photolysis of CpMn(CO)(3) in a hexane/D2O biphasic system.

  DOI：

  10.1021/om1010403