[6-Ph-9-(NC5H4-para-Ph)-arachno-6-CB9H12] | 859740-99-1

• 英文名称: [6-Ph-9-(NC5H4-para-Ph)-arachno-6-CB9H12]
• CAS: 859740-99-1
• 化学式: C₁₈H₂₆B₉N
• 分子量: 353.71
• InChiKey: WBVULXZKOIONGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-苯基吡啶 、 [NEt4](1+)[6-Ph-nido-6-CB9H11](1-) 在 iron(III) chloride hexahydrate 、 HCl 作用下， 以 氯仿 为溶剂， 以56%的产率得到[6-Ph-9-(NC5H4-para-Ph)-arachno-6-CB9H12]
  参考文献：
  名称：

  Polyhedral monocarbaborane chemistry

  摘要：

  Reaction of the ten-vertex [6-Ph-nido-6-CB9H11](-) anion (1) with two-electron donor ligands L, where L is SMe2, NH2Ph, NC5H5, NC5H4-para-CH2Ph, NC5H4-para-Ph or NC9H7 (where NC9H7 is quinoline) in the presence of {FeCl3(OH2)(6)} gives the six neutral arachno ten-vertex monocarbaboranes [6-Ph-9-L-arachno-6-CB9H12], compounds 2, 3, 4, 7, 9 and 11, respectively, isolatable in yields of up to 63%. On prolonged treatment with {FeCl3(OH2)(6)} oxidative cluster closure of the four compounds 4, 7, 9 and 11 that have pyridine-type ligands gives the neutral closo ten-vertex monocarbaboranes [1-Ph-6-L-closo-1-CB9H8], compounds 6, 8, 10 and 12, respectively, in yields of 49-92%. All new species 2, 3, 4, 6, 7, 8, 9, 10, 11 and 12 are characterised by single-crystal X-ray diffraction analysis and NMR spectroscopy. [This paper is an annotated exposition of parts of an oral presentation at the Third Pan-European Meeting of Boron Chemists, EUROBORON-3, Pruhonice, The Czech Republic, September 2004, of which the proceedings constitute this volume of Journal of Organometallic Chemistry] (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.038