di[(2-(5-phenyl-1H-pyrazol-3-yl)-6-(5-phenylpyrazol-3-yl)pyridine)(tri(p-trifluoromethylphenyl)phosphine)ruthenium(II)](μ-chloro) chloride | 1346678-81-6

• 英文名称: di[(2-(5-phenyl-1H-pyrazol-3-yl)-6-(5-phenylpyrazol-3-yl)pyridine)(tri(p-trifluoromethylphenyl)phosphine)ruthenium(II)](μ-chloro) chloride
• CAS: 1346678-81-6
• 化学式: C₈₈H₅₆ClF₁₈N₁₀P₂Ru₂*Cl
• 分子量: 1930.44
• InChiKey: PMCOTGHTHQLNMO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-bis(5-phenyl-1H-pyrazol-3-yl)pyridine 、 水合三氯化钌 、 三(4-三氟甲苯基)膦 在 Et₃N 作用下， 以 乙醇 为溶剂， 以60%的产率得到di[(2-(5-phenyl-1H-pyrazol-3-yl)-6-(5-phenylpyrazol-3-yl)pyridine)(tri(p-trifluoromethylphenyl)phosphine)ruthenium(II)](μ-chloro) chloride
  参考文献：
  名称：

  A novel cationic dinuclear ruthenium complex: Synthesis, characterization and catalytic activity in the transfer hydrogenation of ketones

  摘要：

  A novel cationic dinuclear ruthenium complex [RuCl(HL)(TFTPP)](2) (H2L = 2,6-bis(5-phenyl-1H-pyrazol-3-yl) pyridine; TFTFP = tri(p-trifluoromethylphenyl)phosphine) has been synthesized and characterized by (31)p{H-1} NMR, H-1 NMR, elemental analysis and X-ray crystallography. This complex is the first cationic dinuclear ruthenium complex bearing N-4 ligand characterized by single crystal X-ray analysis. It exhibits good catalytic activity for the transfer hydrogenation of ketones in refluxing 2-propanol. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.09.003