| 850131-82-7

• CAS: 850131-82-7
• 化学式: C₂₉H₄₅GaN₄
• 分子量: 519.426
• InChiKey: OKYIMCBEXYBTNJ-KSWNCPITSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Preparation of Monomeric LGa(NH₂)₂ and of LGa(OH)₂ in the Presence of a N-Heterocyclic Carbene as HCl Acceptor

  摘要：

  The reactions of LGaCl2 (L = HC[C(Me)N(Ar)](2), Ar = 2,6-iPr(2)C(6)H(3)) with NH3 and H2O, respectively, in the presence of a 1,3-bis-tert-butylimidazol-2-ylidene (N-heterocyclic carbene) as acceptor for the HCl lead to unique species of composition LGa(NH2)(2) and LGa(OH)(2) in high yields under mild conditions. LGa(NH2)(2) is the first known monomeric diamide of gallium.

  DOI：

  10.1021/om049304a
• 作为产物：
  描述：

  (2-(2,6-diisopropylphenylamino)-4-(2,6-diisopropylphenyl-imino)-2-pentene-H)GaCl2 、 氨 在 1,3-bis-tert-butylimidazol-2-ylidene 作用下， 以 甲苯 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Preparation of Monomeric LGa(NH₂)₂ and of LGa(OH)₂ in the Presence of a N-Heterocyclic Carbene as HCl Acceptor

  摘要：

  The reactions of LGaCl2 (L = HC[C(Me)N(Ar)](2), Ar = 2,6-iPr(2)C(6)H(3)) with NH3 and H2O, respectively, in the presence of a 1,3-bis-tert-butylimidazol-2-ylidene (N-heterocyclic carbene) as acceptor for the HCl lead to unique species of composition LGa(NH2)(2) and LGa(OH)(2) in high yields under mild conditions. LGa(NH2)(2) is the first known monomeric diamide of gallium.

  DOI：

  10.1021/om049304a