[Co(III)(2,5-DTBCat)2(bpy)][Co(III)Cp2] | 216166-86-8

• 英文名称: [Co(III)(2,5-DTBCat)2(bpy)][Co(III)Cp2]
• 英文别名: [(2,2-bipyridine)Co(3,5-di-tert-butyl-o-catecholate)][cobaltocenium]
• CAS: 216166-86-8；1070452-26-4
• 化学式: C₁₀H₁₀Co*C₃₈H₄₈CoN₂O₄
• 分子量: 844.986
• InChiKey: COUKLQQIUUIRAY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(环戊二烯)钴 、 Co(III)(2,2'-bipyridine)(3,5-di-tert-butylsemiquinonato)(3,5-di-tert-butylcatecholato) 以 二氯甲烷 为溶剂， 以70%的产率得到[Co(III)(2,5-DTBCat)2(bpy)][Co(III)Cp2]
  参考文献：
  名称：

  Intramolecular electron transfer in the mixed-valence [Co(3,5-DTBCat)(3,5-DTBSQ)(bpy)] complex: Beyond valence tautomerism

  摘要：

  The series of complexes [Co(Q)(2)(bpy)](n) (n = -1, 0, +1) that can be derived by partial reduction or oxidation of complex 1, ls-Co(III) has been synthesized and studied. The results support the theoretical calculations which pointed to an intervalence transfer (IT) from the Cat(2) to the SQ ligand rather than a LMCT transition as the origin for the low-energy band transition centered at 2500 nm observed for 1, ls-Co(III). (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.02.069

文献信息

• Valence tautomeric cobalt o-quinone complexes in a dual-mode switching array
  作者：Daniel Ruiz、Jae Yoo、David N. Hendrickson、Ilia A. Guzei、Arnold L. Rheingold

  DOI：10.1039/a802803f

  日期：——

  The characterization of valence tautomeric cobalt complexes with an array of four states, each with different optical and magnetic properties, is reported and it is shown that they can interconvert reversibly between the four states either thermally or by redox processes.

  报告描述了具有四种状态（每种状态都具有不同的光学和磁学特性）的价态同素异形钴络合物的特性，并表明它们可以通过热或氧化还原过程在四种状态之间进行可逆转换。