[RuCl(p-cymene)(1-phenyl-2,5-di(2-pyridyl)phosphole)]BF4 | 511522-60-4

• 英文名称: [RuCl(p-cymene)(1-phenyl-2,5-di(2-pyridyl)phosphole)]BF4
• CAS: 511522-60-4；511522-56-8
• 化学式: BF₄*C₃₄H₃₅ClN₂PRu
• 分子量: 725.967
• InChiKey: HCUHPBHMLGEVPK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 C6H8C2P(2-pyridyl)2(phenyl) 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以82%的产率得到[RuCl(p-cymene)(1-phenyl-2,5-di(2-pyridyl)phosphole)]BF4
  参考文献：
  名称：

  A study of the coordination ability of 2,5-di(2-pyridyl)phospholes on Ru centres

  摘要：

  The coordination behaviour of the readily available 1-phenyl-2,5-di(2-pyridyl)phosphole (NPN) toward Ru centres was investigated. Neutral and ionic compounds of formula [RuCl(p-cymene)(NPN)]TfO (TfO = CF3SO3)... (1), [RuCl(p -cyme-ne)(NPN)]BF4 (2), [RuCl(C6Me6)(NPN)]TfO (3), RuCp'Cl(NPN) [CP' = C5H5 (4), C5Me5 (5)], Ru(C5Me5)(sigma(1)-C8H13)(NPN) (6), RUCl2(NPN)(2) (7) and RuCIH(cod)(NPN) (cod = 1,5-cyclooctadiene) (8) were obtained. Two diastereomers were obtained for 1, 2 and 4, (a, b) while three were found in the case of 8 (a-c). According to NMR spectroscopy, the 2,5-bis(2-pyridyl)phosphole acts as a 1,4-P,N chelate ligand in all cases. This behaviour was confirmed by an X-ray diffraction study performed on complex 1a. Proton transfer studies on complex 8 demonstrated the influence of the molecular structure on the ability to form dihydrogen bridges. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01803-x