[N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(I) chloride | 1422347-55-4

• 英文名称: [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(I) chloride
• CAS: 1422347-55-4
• 化学式: C₁₂H₁₃ClCuN₃Se
• 分子量: 377.214
• InChiKey: IJSDJPYUPHEDCC-JFXLULTRSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯基-2-氨基乙基硒醚 在 苄基三乙基氯化铵 作用下， 以 乙醚 、 乙醇 、 氯仿 、 乙腈 为溶剂， 反应 79.0h， 生成 [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(I) chloride
  参考文献：
  名称：

  Novel copper(II) and cobalt(II) complexes with selenium substituted imidazolyl imines. The molecular and crystal structure of [N-(2-(phenylseleno)ethyl)-N-(imidazol-2-ylmethylene)amine]copper(II) dichloride

  摘要：

  A series of copper(II) and cobalt(II) complexes with novel selenium containing Schiff base ligands obtained from 2- or 3-aminoalkyl phenyl selenides and imidazole carbaldehydes have been synthesized by the interaction of corresponding organic ligands with MCl2 center dot 6H(2)O (M = Cu, Co). The crystal structure of a copper(II) complex with N-(2-(phenylseleno)ethyl)-N-(imidazolyl-2-ylmethylene)amine has been solved by a single-crystal X-ray diffraction method. The copper(II) ions are coordinated by the imine and imidazole nitrogen atoms of organic ligands and two chloride anions in a distorted square planar geometry. The electrochemical investigations of the synthesized ligands and complexes have been made by cyclic voltammetry method. It is established that the first stage of complexes reduction takes place to metal and the reduced forms of complexes are stable in the solution. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.11.039