[CuCl(1,4-bis(N-1-methylimidazol-2-ylmethyl)-1,4-diazacycloheptane)]ClO4 | 488090-65-9

• 英文名称: [CuCl(1,4-bis(N-1-methylimidazol-2-ylmethyl)-1,4-diazacycloheptane)]ClO4
• CAS: 488090-65-9
• 化学式: C₁₅H₂₄ClCuN₆*ClO₄
• 分子量: 486.845
• InChiKey: RTAHLPPRPHAJCO-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 1,4-bis(N-1-methylimidazol-2-ylmethyl)-1,4-diazacycloheptane tetrahydrochloride trihydrate 在 KOH 作用下， 以 甲醇 、 水 为溶剂， 以70%的产率得到[CuCl(1,4-bis(N-1-methylimidazol-2-ylmethyl)-1,4-diazacycloheptane)]ClO4
  参考文献：
  名称：

  Synthesis, crystal structure and properties of the CuII complex of a tetradentate imidazole-functionalized diazamesocyclic ligand, 1,4-bis(N-1-methylimidazol-2-yl-methyl)-1,4-diazacycloheptane

  摘要：

  A new potential tetradentate ligand, 1,4-bis(N-1-methylimidazol-2-ylmethyl)-1,4-diazacycloheptane (L), together with its Cu-II complex [CuLCl]ClO4 (1), has been reported. The crystal structure of 1, determined by single-crystal X-ray analysis, shows that it is in chiral P2(1)2(1)2(1) space group. The Cu-II centre is penta-coordinated in square pyramidal geometry and the diazacycloheptane (DACH) ring adopts normal boat configuration. The most striking feature of this complex is the formation of a 3D network bridged through the C-H...Cl hydrogen bonds with the perchlorate anions in the cavities, and stabilized via pi-pi stacking interactions along the a-direction. The solution behaviour of 1 has been further investigated by UV/Vis and ESR techniques. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(02)00166-7