| 1418226-83-1

• CAS: 1418226-83-1
• 化学式: C₃₇H₃₂AuP₂Si*Cl₄Ga
• 分子量: 975.196
• InChiKey: GIKKXMLPZVIQBO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [2-(diphenylphosphino)phenyl]lithium 以 二氯甲烷 、 甲苯 为溶剂， 反应 0.83h， 生成
  参考文献：
  名称：

  σ-SiH Complexes of Copper: Experimental Evidence and Computational Analysis

  摘要：

  Copper and gold complexes 2-4 of the diphosphine-hydrosilane [PH2P(o-C6H4)](2)MeSiH ligand 1 have been prepared, and their bonding situation has been analyzed experimentally (NMR, IR, X-ray diffraction) and computationally (geometry optimizations, NBO analyses). The sigma-SiH bond remains pendant in the gold complex 4 but engages into a weak side-on coordination to copper. This bonding interaction slightly strengthens when the metal becomes more electron deficient, consistent with essentially pure sigma-SiH-to-copper donation. Complexes 2 and 3 provide very rare examples of a-bond coordination to a coinage metal.

  DOI：

  10.1021/om301211c