indium perchlorate | 62763-56-8

• 英文名称: indium perchlorate
• 英文别名: indium(I) perchlorate；Indium(1+);perchlorate
• CAS: 62763-56-8
• 化学式: ClO₄*In
• 分子量: 214.271
• InChiKey: GGRZMUYVGQGAOJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -5.14
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  indium perchlorate 、 1,10-bis<1-phenyl-3-methyl-5-hydroxy-4-pyrazolyl>-1,10-decanedione 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Analytical and spectroscopic study of indium extraction with 1,10-Bis(1-phenyl-3-methyl-5-hydroxy-4-pyrazolyl)-1,10-decanedione and its mixtures with Tri-n-octylphosphine oxide

  摘要：

  Complex organic phases are obtained by extraction of indium from 1 M perchlorate media with chloroform solutions of 1,10-bis(1-phenyl-3-methyl-5-hydroxy-4-pyrazolyl)-1,10-decanedione, "HL-8-LH". PMR and analytical data show that, at low pH and for low extractant concentrations, four extracted species are present: In(L-8-L) (L-8-LH), In2(L-8-L)3, In(L-8-LH)3 and In2(L-8-L)2 (L-8-LH)2. The corresponding extraction constants have been estimated, resp. 0.0 < log K12 < 1.0; 1.2 < log K23 < 2.2; 1.0 < log K13 < 2.2 and 0 < log K24 < 3. At highest pH's, polymeric species are formed.The extractible complex In2(L-8-L)3 has been synthesized. It contains two "(L-8-L)In" moieties where L-8-L2- acts as a bis-chelatant folded on the indium atom, linked by a L-8-L2- bridge. This complex slowly rearranges in chloroform solutions to form polymeric species.A weak synergy is observed by adding tri-n-octylphosphine oxide, "TOPO", to the extraction solvent. The organic extraction phase mainly contains In2(L-8-L)3 (TOPO)2. The corresponding extraction constant is log K232 = 6.6 +/- 0.2. P-31-NMR shows that this complex is not formed by TOPO addition in the organic phase, contrary to the usual description of the synergistic effect.

  DOI：

  10.1007/bf00809797
• 作为产物：
  描述：

  silver perchlorate 在 indium amalgam 作用下， 以 乙腈 为溶剂， 生成 indium perchlorate
  参考文献：
  名称：

  高氯酸铟（I），四氟硼酸盐和六氟磷酸盐的制备

  摘要：

  高氯酸铟（I），四氟硼酸铟和六氟磷酸盐是通过铟汞齐与亚化学计量的乙腈中适当的银（I）盐的化学反应，然后部分蒸发溶液而制备的。盐的身份已被定量测定总铟的，在建立予，和相应的阴离子。

  DOI：

  10.1039/dt9770000170