[Ag(ClO4)(1,2-(PCy2)2-1,2-C2B10H10)]*CH2Cl2 | 1310710-32-7

• 英文名称: [Ag(ClO4)(1,2-(PCy2)2-1,2-C2B10H10)]*CH2Cl2
• 英文别名: [Ag(ClO4)(1,2-(dicyclohexylphosphino)2-1,2-C2B10H10)]*dichloromethane
• CAS: 1310710-32-7
• 化学式: CH₂Cl₂*C₂₆H₅₄AgB₁₀ClO₄P₂
• 分子量: 829.024
• InChiKey: DBEOKFPMXPCJKZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯甲烷 、 1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane 、 silver perchlorate 以 二氯甲烷 为溶剂， 以49%的产率得到[Ag(ClO4)(1,2-(PCy2)2-1,2-C2B10H10)]*CH2Cl2
  参考文献：
  名称：

  1D and 2D supramolecular structures of silver carborane dicyclohexylphosphine complexes constructed by C–H⋯H–B dihydrogen bonding interactions

  摘要：

  Five new carborane dicyclohexylphosphine complexes, [Ag-2(mu-I)(2){1,2-(P Cy-2)(2)-1,2-C2B10H10}(2)] (1), [Ag-2(SCH)(2){1,2-(PCy2)(2)-1,2-C2B10H10}(2)](n)center dot CH2Cl2 (2), [Ag(ClO){1,2-(PCy2)(2)-1,2-C2B10H10}]center dot CH2Cl2 (3), [Ag-2(mu-NO3)(2){1,2-(PCy2)(2)-1,2-C2B10H10}(2)]center dot CH2Cl2 (4) and [Ag(SC6H4COOH){1,2-(PCy2)(2)-1,2-C2B10H10}(2)]center dot CH2Cl2 (5), have been synthesized by the reactions of 1,2-bis(dicyclohexylphosphino)-1,2-dicarba-closo-dodecaborane with AgX (X = I, SCN, ClO4, NO3 and SC6H4COOH) in CH2Cl2. The structures of the five complexes were characterized by elemental analysis, FT-IR, H-1, C-13, B-11 and P-31 NMR spectroscopy. X-ray structure analysis revealed that the structures of the complexes can be classified into three types. Complexes 1 and 4 are di-mu-X-bridged structures and complexes 3 and 5 are mononuclear structures, while complex 2 is a chain-like polymer. Complexes 1 and 2 form 2D supramolecular networks and complexes 3, 4 and 5 form 1D chains via C-H center dot center dot center dot H-B dihydrogen bonding interactions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.02.052