[Cu(HDKN)Cl2] | 1270155-60-6

• 英文名称: [Cu(HDKN)Cl2]
• 英文别名: [Cu(di-2-pyridyl ketone nicotinoylhydrazone)Cl2]
• CAS: 1270155-60-6
• 化学式: C₁₇H₁₃Cl₂CuN₅O
• 分子量: 437.775
• InChiKey: XQZHSEBWROONGR-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  di-2-pyridyl ketone nicotinoyl hydrazone hemihydrate 、 copper dichloride 以 甲醇 为溶剂， 以75%的产率得到[Cu(HDKN)Cl2]
  参考文献：
  名称：

  Versatile binding properties of a di-2-pyridyl ketone nicotinoylhydrazone ligand: Crystal structure of a Cu(II) complex

  摘要：

  Six new copper complexes of di-2-pyridyl ketone nicotinoylhydrazone (HDKN) have been synthesized. The complexes have been characterized by a variety of spectroscopic techniques and the structure of [Cu(DKN)(2)]center dot H2O has been determined by single crystal X-ray diffraction. The compound [Cu(DKN)(2)].H2O crystallized in the monoclinic space group P2(1) and has a distorted octahedral geometry. The IR spectra revealed the presence of variable modes of chelation for the investigated ligand. The EPR spectra of compounds [Cu-2(DKN)(2)(mu-N-3)(2)] and [Cu-2(DKN)(2)(mu-NCS)(2)] in polycrystalline state suggest a dimeric structure as they exhibited a half field signal, which indicate the presence of a weak interaction between two Cu(II) ions in these complexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2010.11.032