[Cd(pyrazole)Cl2] | 64869-46-1

• 英文名称: [Cd(pyrazole)Cl2]
• 英文别名: [Cd(μ-Cl)2(pyrazole)2]n；[Cd(μ-Cl)2(HPz)2]n
• CAS: 64869-46-1
• 化学式: C₆H₈CdCl₂N₄
• 分子量: 319.472
• InChiKey: MGSYVHGWXMLIGF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Cd(pyrazole)Cl2] 、 sodium thiocyanide 以 甲醇 、 水 为溶剂， 以70%的产率得到[Cd(μ-1,3-SCN)2(pyrazole)2]n
  参考文献：
  名称：

  Pyrazolyl coordination polymers of cadmium(II)

  摘要：

  The coordination polymers [Cd(mu-Cl)(2)(HPz)(2)](n) (1) and [Cd(mu-1,3-SCN)(2)(HPz)(2)](n) (2) (HPz = pyrazole) have been prepared and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. Both complexes exhibited chain structures made by linear arrays of Cd(II) bridged by chloro (1) or inversely related 1,3-SCN groups (2) and the pyrazole ligands at the apical. sites. Intermolecular hydrogen bonds and another non-covalent interactions are responsible for the self-assembly of linear chains into 2D networks. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.11.015
• 作为产物：
  描述：

  吡唑 、 aqueous cadmium chloride 以 甲醇 为溶剂， 以45%的产率得到[Cd(pyrazole)Cl2]
  参考文献：
  名称：

  Pyrazolyl coordination polymers of cadmium(II)

  摘要：

  The coordination polymers [Cd(mu-Cl)(2)(HPz)(2)](n) (1) and [Cd(mu-1,3-SCN)(2)(HPz)(2)](n) (2) (HPz = pyrazole) have been prepared and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction. Both complexes exhibited chain structures made by linear arrays of Cd(II) bridged by chloro (1) or inversely related 1,3-SCN groups (2) and the pyrazole ligands at the apical. sites. Intermolecular hydrogen bonds and another non-covalent interactions are responsible for the self-assembly of linear chains into 2D networks. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.11.015