[RuCl2(η6-p-cymene)(P(OC2H5)2C6H5)] | 1174671-12-5

• 英文名称: [RuCl2(η6-p-cymene)(P(OC2H5)2C6H5)]
• 英文别名: [(η6-p-cymene)RuCl2(PPh(OEt)2)]；(η6-p-cymene)RuCl2(P(OEt)2Ph)；RuCl2(η6-p-cymene)(PPh(OEt)2)；[RuCl2(η6-p-cymene)P(OEt)2Ph]；[RuCl2(η6-p-cymene)PPh(OEt)2]
• CAS: 1174671-12-5
• 化学式: C₂₀H₂₉Cl₂O₂PRu
• 分子量: 504.399
• InChiKey: NYIQWYQJIQQBNT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [RuCl2(η6-p-cymene)(P(OC2H5)2C6H5)] 、 四苯硼钠 、 肼 以 乙醇 、 二氯甲烷 为溶剂， 以76%的产率得到[(η6-p-cymene)RuCl(P(OEt)2Ph)(NH2NH2)][BPh4]
  参考文献：
  名称：

  钌和半三明治肼配合物的制备及反应活性

  摘要：

  肼复合物[的MC1（η 6 - p -cymene）（RNHNH 2）L] BPH 4（1 - 6）[M =钌，锇; R = H，Me，Ph；L = P（OET）3，PPH（OET）2，PPH 2 OET]通过使二氯络合物的MC1制备2（η 6 - p L至反应与肼RNHNH -cymene）2在NaBPh的存在4。钌配合物的治疗将[RuCl（η 6 - p -cymene）（RNHNH 2）L] BPH 4用的Pb（OAC）4导致乙酸复杂的[Ru（κ2 -O 2 CCH 3）（η 6 - p -cymene）L] BPH 4（7）。取而代之的是，锇衍生物[OSCL（η反应6 - p -cymene）（CH 3 NHNH 2）L] BPH 4用的Pb（OAC）4得到methyldiazenido络合物[OS（CH 3 Ñ 2）（η 6 - p -cymene）L}] BPh 4（8）。用盐

  DOI：

  10.1016/j.jorganchem.2011.09.011
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 苯基膦酸二乙酯 以 二氯甲烷 为溶剂， 以90%的产率得到[RuCl2(η6-p-cymene)(P(OC2H5)2C6H5)]
  参考文献：
  名称：

  钌(II)和锇(II)的氰胍和乙基氰胺配合物的制备

  摘要：

  氰胍配合物[MCl{η 1 -N≡CN(H)C(NH 2 )=NH}-(η 6 -p-伞花烃)(PR 3 )]BPh 4 [M = Ru, Os; PR 3 = P(OEt) 3 、PPh(OEt) 2 、PPh 2 OEt、PiPr 3 ]通过用氰胺N≡CNH 2 处理化合物[MCl 2 (η 6 -p-伞花烃)(PR3)]来制备。或者，通过处理[MCl 2 (η 6 - p-伞花烃)(PR 3 )]与氰基胍。二乙基氰胺配合物[MCl(N≡CNEt 2 )(η 6 -p-伞花烃)(PR 3 )]-BPh 4 也通过处理[MCl 2 (η 6-p-伞花烃)-(PR 3 )] 与过量的 N≡CNEt 2 配合物进行了光谱表征 (IR, 1 H, 31 P, 13 C NMR) 和 [RuCl{N≡CN (H)C(NH 2 )=NH}(η 6 -p-伞花烃)-(PPh(OEt) 2 }]BPh

  DOI：

  10.1002/ejic.200900639

文献信息

• Preparation and reactivity of p-cymene complexes of ruthenium and osmium incorporating 1,3-triazenide ligands
  作者：Gabriele Albertin、Stefano Antoniutti、Jesús Castro、Stefano Paganelli

  DOI：10.1016/j.jorganchem.2010.05.028

  日期：2010.8

  complexes MCl(η2-1,3-ArNNNAr)(η6-p-cymene) (M = Ru, Os) were also prepared by allowing [MCl(μ-Cl)(η6-p-cymene)]2 to react with 1,3-diaryltriazene in the presence of triethylamine. p-Cymene complexes MCl2(η6-p-cymene)L reacted with equimolar amounts of 1,3-ArNNN(H)Ar triazene to give both triazenide complexes [M(η2-1,3-ArNNNAr)(η6-p-cymene)L]BPh4 and amine derivatives [MCl(ArNH2)(η6-p-cymene)L]BPh4

  p -Cymene络合物的MC1 2（η 6 - p -cymene）L [M =钌，锇; L = P（OET）3，PPH（OET）2，（CH 3）3 CNC]通过允许制备的MC1（μ-Cl）的（η 6 - p -cymene）] 2与亚磷酸酯或反应叔丁基异氰化物。的MC1的治疗2（η 6 - p -cymene）L-络合物与1,3- ARN NN（H）中的Ar三氮烯和过量净的3得到阳离子triazenide衍生物[M（η 2 -1,3- ArNNNAr）（ η 6 - p-cymene）L] BPh 4（Ar = Ph，p-甲苯基）。中性triazenide络合物的MC1（η 2 -1,3- ArNNNAr）（η 6 - p -cymene）（M =钌，锇）也通过允许制备的MC1（μ-Cl）的（η 6 - p -cymene）] 2在三乙胺存在下与1,3-二芳基三氮烯反应。p -Cymene络合物的MC1
• Preparation of Pyrazole–Pyrazolate Half‐Sandwich Complexes of Ruthenium and Osmium
  作者：Gabriele Albertin、Stefano Antoniutti、Jesús Castro、Soledad García‐Fontán

  DOI：10.1002/ejic.201000799

  日期：2011.2

  [MCl(η6-p-cymene)(HRpz)L]BPh4 (1–8) and imidazole (HIm) complexes [MCl(η6-p-cymene)(HIm)L]BPh4 (9–10) [M = Ru, Os; R = H, 3-Me, 3,5-Me2; L = P(OEt)3, PPh(OEt)2, PPh2OEt, CNtBu] were prepared by allowing the dichloro compounds MCl2(η6-p-cymene)L to react with the appropriate azole in the presence of NaBPh4. Treatment of the dichloro complexes with an excess of both pyrazole and NEt3 yielded the pyrazole–pyrazolate

  吡唑 (HRpz) [MCl(η6-p-cymene)(HRpz)L]BPh4 (1-8) 和咪唑 (HIm) 复合物 [MCl(η6-p-cymene)(HIm)L]BPh4 (9-10) [M = Ru, Os; R = H, 3-Me, 3,5-Me2; L = P(OEt)3、PPh(OEt)2、PPh2OEt、CNtBu]是通过让二氯化合物 MCl2(η6-p-伞花烃)L 在 NaBPh4 存在下与适当的唑反应来制备的。用过量的吡唑和 NEt3 处理二氯配合物产生吡唑-吡唑衍生物 [M(Rpz)(η6-p-cymene)(HRpz)L]BPh4 (11-14)。相反，羰基化合物 RuCl2(η6-p-cymene)(CO) 与吡唑或咪唑反应生成双唑配合物 [MCl(η6-p-cymene)(HRpz)2]BPh4 或 [MCl(η6-p-cymene) )(HIm)2]BPh4 (15–17)。配合物通过光谱（IR
• Preparation of (η⁵-Alkoxyfluorenyl)(η⁶-<i>p-</i>Cymene)-Sandwich Ruthenium(II) Complexes
  作者：Gabriele Albertin、Stefano Antoniutti、Fabio Callegaro、Jesús Castro

  DOI：10.1021/om900350n

  日期：2009.8.10

  Diazoalkane complexes [RuCl(N(2)CArlAr2)(n(6)-p-cymene)P]BPh4 [Arl = Ph; Ar2 = Ph or p-tolyl; P=PPh(OEt)(2) or P(OEt)(3)] were prepared by allowing p-cymene complexes RuCl2 (n(6)-p-cymene)P to react with diaryldiazoalkane ArlAr2CN(2). Treatment of the triisopropylphosphine complex RuCl2(n(6)-p-cymene)(P'Pr-3) with 9-diazofluorene yielded the (n(5)-alkoxyfluorenyl)(n(6)-p-cymene)-sandwich derivative [Ru(n(5)-RO-fluorenyl)(n(6)-p-cymene)]BPh4 (R = Mc. Et) The complexes were characterized spectroscopically (IR and H-1, C-13. P-31 NMR) and by X-ray crystal structure determination of the [Ru(n(5)-EtO-fluorenyl)(n(6)-cymene]BPh4 derivative.
• Preparation of imine complexes of ruthenium and osmium stabilised by [MCl(η 6-p-cymene)(PR3)]+ fragments
  作者：Gabriele Albertin、Stefano Antoniutti、Jesús Castro

  DOI：10.1016/j.jorganchem.2009.11.008

  日期：2010.2

  Imine complexes [MCl(eta (6)-p-cymene)eta(1)-NH=C(H)Ar}(PR3)]BPh4 (1-3) [M = Ru, Os; PR3 = PPh(OEt)(2), PPh2OEt; Ar = Ph, p-tolyl] were prepared by reacting MCl2(eta (6)-p-cymene)(PR3) precursors with benzyl azide ArCH2N3 in the presence of NaBPh4. Benzophenone-imine complexes [MCl(eta (6)-p-cymene)eta(1)-NH=CPh2}(PR3)]BPh4 (4-6) [M = Ru, Os; PR3 = PPh(OEt)(2), PPh2OEt] were also prepared by allowing MCl2(eta 6-p-cymene)(PR3) to react with Ph2C=NH in the presence of NaBPh4. The complexes were characterised spectroscopically (IR, H-1, C-13, P-31, N-15 NMR) and by X-ray crystal structure determination of [RuCl(eta (6)-p-cymene)eta(1)-NH=C(H)-p-tolyl}PPh(OEt)(2)}]BPh4 (1b). (C) 2009 Elsevier B.V. All rights reserved.